[Ni<sub>2</sub>O(l-Asp)(H<sub>2</sub>O)<sub>2</sub>]·4H<sub>2</sub>O: A Homochiral 1D Helical Chain Hybrid Compound with Extended Ni−O−Ni Bonding
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The hydrothermally synthesized 1D homochiral nickel aspartate oxide [Ni2O(l-Asp)(H2O)2]·4H2O is based on infinite helical chains of edge- and corner-sharing nickel octahedra. It represents the first example of a chiral one-dimensional compound with an extended helical TM−O−TM subnetwork synthesized as an optically pure product. Its structure was determined ab initio by real-space methods from laboratory powder diffraction data.
创建时间：
2004-03-17
