Hydrogen Peroxide Complex of Zinc
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https://figshare.com/articles/dataset/Hydrogen_Peroxide_Complex_of_Zinc/2105059
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资源简介：
Metal(H2O2) complexes have been implicated
in kinetic and computational studies but have never been observed.
Accordingly, H2O2 has been described as a very
weak ligand. We report the first metal(H2O2)
adduct, which is made possible by incorporating intramolecular hydrogen-bonding
interactions with bound H2O2. This ZnII(H2O2) complex decays in solution by a second-order
process that is slow enough to enable characterization of this species
by X-ray crystallography. This report speaks to the intermediacy of
metal(H2O2) adducts in chemistry and biology
and opens the door to exploration of these species in oxidation catalysis.
创建时间：
2016-02-12
