Synthesis of a Coordinatively Labile Gold(III) Methyl Complex
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https://figshare.com/articles/dataset/Synthesis_of_a_Coordinatively_Labile_Gold_III_Methyl_Complex/2638354
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资源简介：
Stable and isolable cyclometalated monomethyl Au(III) complexes are readily available from the precursor (tpy)Au(Me)Cl, prepared from (tpy)AuCl2 and excess SnMe4. Reaction of (tpy)Au(Me)Cl with suitable silver salts generates (tpy)Au(Me)(X) (X = OAc, OTf). Ligand exchange reactions with (tpy)Au(Me)(OTf) provide the cationic monomethyl Au(III) adducts [(tpy)Au(Me)(L)][OTf] (L = PPh3, THT).
创建时间：
2011-06-27
