Efficient Benzylic and Aliphatic C–H Oxidation with Selectivity for Methylenic Sites Catalyzed by a Bioinspired Manganese Complex
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下载链接：
https://figshare.com/articles/dataset/Efficient_Benzylic_and_Aliphatic_C_H_Oxidation_with_Selectivity_for_Methylenic_Sites_Catalyzed_by_a_Bioinspired_Manganese_Complex/2321320
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资源简介：
A benzimidazole-based
nonheme manganese complex efficiently catalyzes benzylic, aliphatic
C–H as well as tertiary C–H oxidation with hydrogen
peroxide as the oxidant in the presence of acetic acid as additive. 18O labeling experiments suggest the reaction may proceed via
a high-valent manganese-oxo intermediate.
创建时间：
2016-02-18
