Synthesis and Structural Characterization of a Cyclen-Derived Molecular Cage
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https://figshare.com/articles/dataset/Synthesis_and_Structural_Characterization_of_a_Cyclen_Derived_Molecular_Cage/2103115
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资源简介:
Reaction of a tetrafunctionalized
cyclen derivative containing
four aldehyde groups with an appropriate diamine followed by reduction
and demetalation highly efficiently affords a bis(cyclen)-derived
molecular cage. Potentiometric investigations show that this compound
forms dimetallic complexes with copper(II), with the two metal ions
selectively coordinated to the cyclen units. X-ray crystallography
indicates that these complexes could give rise to new cascade complexes
after incorporation of anions between the metal centers.
创建时间:
2016-02-12



