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Synthesis and Structural Characterization of a Cyclen-Derived Molecular Cage

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https://figshare.com/articles/dataset/Synthesis_and_Structural_Characterization_of_a_Cyclen_Derived_Molecular_Cage/2103115
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Reaction of a tetrafunctionalized cyclen derivative containing four aldehyde groups with an appropriate diamine followed by reduction and demetalation highly efficiently affords a bis­(cyclen)-derived molecular cage. Potentiometric investigations show that this compound forms dimetallic complexes with copper­(II), with the two metal ions selectively coordinated to the cyclen units. X-ray crystallography indicates that these complexes could give rise to new cascade complexes after incorporation of anions between the metal centers.
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2016-02-12
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