Ruthenium- and Copper-Catalyzed Enantioselective Propargylic Alkylation of Propargylic Alcohols with β-Keto Phosphonates
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https://figshare.com/articles/dataset/Ruthenium_and_Copper_Catalyzed_Enantioselective_Propargylic_Alkylation_of_Propargylic_Alcohols_with_Keto_Phosphonates/2529073
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资源简介:
The enantioselective propargylic alkylation of propargylic
alcohols
with β-keto phosphonates in the presence of a thiolate-bridged
diruthenium complex and a copper complex as cocatalysts gives the
corresponding propargylic alkylated products in excellent yields with
high diastereo- and enantioselectivities (up to 97% ee).
创建时间:
2012-04-23



