遇见数据集

Persistent Ambipolar Heptacenes and Their Redox Species [Data]

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heiDATA2022-01-01 更新2026-05-11 收录
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Research Data associated with the related publication. Sixfold TIPS-ethynylation combined with fourfold bromination of the armchair edges furnishes a long-lived, soluble heptacene; π-extension via Stille coupling accesses a persistent tetrabenzononacene. Both types of acenes were stabilized best by double TIPS-ethynylation on every other benzene ring. Tetrabromoheptacene is an ambipolar transistor material (up to 0.036 cm2/Vs n channel), which was corroborated by generation of its monoanion and monocation.

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2022-01-01
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