Catalytic Enantioselective Desymmetrization of <i>meso</i>-Diamines: A Dual Small-Molecule Catalysis Approach
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The desymmetrization of meso-diamines was accomplished via enantioselective monobenzoylation facilitated by the cooperative action of two small-molecule catalysts. A chiral acyl-transfer reagent is formed in situ through the interplay of benzoic anhydride, 4-(dimethylamino)pyridine as a nucleophilic catalyst, and a chiral amide–thiourea cocatalyst.
创建时间：
2011-09-21
