Paramagnetic Active Site Models for the Molybdenum−Copper Carbon Monoxide Dehydrogenase
收藏NIAID Data Ecosystem2026-03-06 收录
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New paramagnetic, heterobimetallic Mo/Cu complexes featuring the Mo(O)(μ-S)Cu core of O. carboxidovorans carbon monoxide dehydrogenase have been synthesized and structurally and spectroscopically characterized. The complexes exhibit EPR spectra (left graphic) indicative of extensive electron delocalization across the Mo-S-Cu core, in agreement with computational studies identifying the singly-occupied molecular orbital (right graphic).
创建时间：
2016-05-05
