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Rh-Mediated Enantioselective Synthesis, Crystal Structures, and Photophysical/Chiroptical Properties of Phenanthrenol-Based [9]Helicene-like Molecules

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https://figshare.com/articles/dataset/Rh-Mediated_Enantioselective_Synthesis_Crystal_Structures_and_Photophysical_Chiroptical_Properties_of_Phenanthrenol-Based_9_Helicene-like_Molecules/4300268
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The enantioselective synthesis of phenanthrenol-based [9]­helicene-like molecules has been achieved via the rhodium-mediated intramolecular [2 + 2 + 2] cycloadditions of 3-phenanthrenol-linked triynes. Crystal structures and photophysical/chiroptical properties of these [9]­helicene-like molecules were compared with the corresponding [7]­helicene-like molecules.
创建时间:
2016-12-09
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