Bifunctional Ruthenium(II) Hydride Complexes with Pendant Strong Lewis Acid Moieties: Structure, Dynamics, and Cooperativity
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https://figshare.com/articles/dataset/Bifunctional_Ruthenium_II_Hydride_Complexes_with_Pendant_Strong_Lewis_Acid_Moieties_Structure_Dynamics_and_Cooperativity/2444245
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资源简介:
The synthesis of a novel class of bifunctional ruthenium
hydride
complexes incorporating Lewis acidic BR2 moieties is reported.
Determination of the molecular structures in the solid state and in
solution provided evidence for tunable interaction between the two
functionalities. Cooperative effects on the reactivity of the complexes
were demonstrated including the activation of small Lewis basic molecules
by reversible anchoring at the boron center.
创建时间:
2016-02-19



