Synthesis, Characterization, and Thermolysis of Dibenzo-7-dimethylgermanorbornadiene
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https://figshare.com/articles/dataset/Synthesis_Characterization_and_Thermolysis_of_Dibenzo_7_dimethylgermanorbornadiene/2123764
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The dibenzo-7-dimethylgermanorbornadiene Me2GeA (A = C14H10) has been synthesized in one step by treatment of MgA·3THF with Me2GeCl2 in tetrahydrofuran (−35 °C) and isolated in 69% yield. The thermolysis of Me2GeA in toluene leads to the effective expansion of the bicyclic framework to the dibenzo-7,8-tetramethyldigermabicyclo[2.2.2]octadiene (Me2Ge)2A, isolated in 71% yield (based on germanium). The bicyclic compounds Me2GeA and (Me2Ge)2A have been characterized by single-crystal X-ray diffraction studies and their structures discussed.
创建时间：
2016-02-12
