Rational Design of CH/π Interaction Sites in a Basic Resolving Agent
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https://figshare.com/articles/dataset/Rational_Design_of_CH_Interaction_Sites_in_a_Basic_Resolving_Agent/3318610
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资源简介：
A novel synthetic basic resolving agent, cis-1-aminobenz[f]indan-2-ol (ABI), was rationally designed
by introducing effective CH/π interaction sites to cis-1-aminoindan-2-ol (AI), whose chiral recognition
ability has been reported from our laboratory. ABI was applicable to a wide variety of racemic
arylalkanoic acids and showed moderate to excellent chiral recognition ability, which was obviously
higher than that of AI. The fundamental and important role of CH/π interactions, such as tunable
CH(sp2)/π and CH(sp3)/π interactions, in the chiral recognition by ABI was revealed by X-ray
crystallographic study.
创建时间：
2016-05-06
