Enantioselective Synthesis of Cephalimysins B and C
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https://figshare.com/articles/dataset/Enantioselective_Synthesis_of_Cephalimysins_B_and_C/4616602
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资源简介:
The
first synthesis of cephalimysins B and C is reported. The route
features a Ni(II)–diamine-catalyzed enantioselective conjugate
addition of a densely substituted 3(2H)-furanone
and an efficient dihydroxylation–lactonization sequence as
key steps in the assembly of the spirocyclic core. The fully synthetic
strategy is amenable to analog preparation.
创建时间:
2017-02-03



