Bimetallic Nickel Aluminun Mediated <i>Para</i>-Selective Alkenylation of Pyridine: Direct Observation of η<sup>2</sup>,η<sup>1</sup>-Pyridine Ni(0)−Al(III) Intermediates Prior to C−H Bond Activation
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We have presented new amino-NHC Ni−Al complex mediated para C−H bond activation for pyridine and quinolin, and isolated for the first time the intermediate structure of a bimetallic η2,η1-pyridine nickel aluminum complex prior to its C−H activation, which serves as key evidence for bimetallic catalysis.
创建时间:
2010-09-01



