Catalytic Asymmetric Diaziridination
收藏Figshare2016-02-19 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Catalytic_Asymmetric_Diaziridination/2430778
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资源简介：
The first catalytic enantio- and diastereoselective synthesis of diaziridines is presented. Aziridination of N-tosyl aldimines applying modified hydroxylamine under asymmetric phase-transfer catalysis furnished optically active diaziridines. The diaziridines are formed as a single diastereomer in up to 96% ee, containing two orthogonal N-protecting groups, which can be deprotected selectively.
创建时间：
2016-02-19
