five

Structural and Electronic Behavior of Unprecedented Five-Coordinate Iron(III) and Gallium(III) Complexes with a New Phenol-Rich Electroactive Ligand

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https://figshare.com/articles/dataset/Structural_and_Electronic_Behavior_of_Unprecedented_Five_Coordinate_Iron_III_and_Gallium_III_Complexes_with_a_New_Phenol_Rich_Electroactive_Ligand/3239401
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A new asymmetric pentadentate ligand was designed to impose low symmetry to trivalent ions. Five-coordinate Fe3+ and Ga3+ complexes were investigated by crystallographic, electrochemical, and electron paramagnetic resonance methods showing enhanced redox reversibility. Calculations were performed to account for the observed trends.
创建时间:
2006-02-06
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