Structural and Electronic Behavior of Unprecedented Five-Coordinate Iron(III) and Gallium(III) Complexes with a New Phenol-Rich Electroactive Ligand
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A new asymmetric pentadentate ligand was designed to impose low symmetry to trivalent ions. Five-coordinate Fe3+ and Ga3+ complexes were investigated by crystallographic, electrochemical, and electron paramagnetic resonance methods showing enhanced redox reversibility. Calculations were performed to account for the observed trends.
创建时间:
2006-02-06



