Decasilahexahydrotriquinacene and Decasilaisotwistane: σ Conjugation on a Bowl Surface
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下载链接：
https://figshare.com/articles/dataset/Decasilahexahydrotriquinacene_and_Decasilaisotwistane_Conjugation_on_a_Bowl_Surface/4685353
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资源简介：
The first bowl-shaped
oligosilane, hexadecamethyldecasilahexahydrotriquinacene
(1), and a related oligosilane, hexadecamethyldecasilaisotwistane
(2), were synthesized, and their structures and properties
were studied. The results revealed importance of σ conjugation
on a bowl surface: the HOMOs of 1 are σ orbitals
delocalized on the bowl surface, whereas the LUMO is a pseudo π*
orbital on the convex and concave sides of the bowl surface.
创建时间：
2017-02-23
