Two New Copper Azido Polymorphs: Structures, Magnetic Properties, and Effects of “Noninnocent” Reagents in Hydrothermal Methods
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Two new 3D copper(II) azido isomers, [Cu(N3)(nic)]∞ (1 and 2) (nic = nicotinate), have been synthesized and characterized. To the best of our knowledge, 1 is the first metal azido complex showing rutile-type topology, while 2 is a chiral compound obtained by spontaneous resolution upon crystallization.
创建时间：
2016-06-03
