Flash Communication: Reductive Cleavage of Dinitrogen Mediated by a Heterometallic Uranium–Gold Complex
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Treatment of a heterometallic uranium–gold complex with KC8 facilitates the six-electron reduction of N2, yielding a multimetallic U4Au4N2 complex featuring two μ3-bridging nitrido ligands. This work represents a rare example of N2 cleavage promoted by a uranium–transition metal species and highlights the potential of heterometallic cooperativity for small-molecule activation.
创建时间：
2025-12-04
