Highly Diastereoselective Addition of Cinnamylzinc Derivatives to α-Chiral Carbonyl Compounds
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下载链接：
https://figshare.com/articles/dataset/Highly_Diastereoselective_Addition_of_Cinnamylzinc_Derivatives_to_Chiral_Carbonyl_Compounds/2965123
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资源简介：
Cinnamylzinc reagents react with cyclic and acyclic α-chiral ketones under very mild conditions (−78 °C, 1 h), yielding the corresponding
homoallylic alcohols bearing three adjacent stereocenters with high diastereoselectivity. An extension of this reaction to enantioenriched
α-chiral ketones is also described.
创建时间：
2016-06-03
