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Biphenylene-Bridged Dinuclear Group 4 Metal Complexes: Enhanced Polymerization Properties in Olefin Polymerization

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Biphenylene_Bridged_Dinuclear_Group_4_Metal_Complexes_Enhanced_Polymerization_Properties_in_Olefin_Polymerization/3277036
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资源简介:
The well-defined, novel dinuclear group 4 metal complexes [4,4‘-(C6H4)2(C5Me4)2][CpZrX2]2 (X = Cl (2a), Me (2b)), [4,4‘-(C6H4)2(C5Me4)2][TiCl3]2 (3), and [4,4‘-(C6H4)2(C5Me4)2][Ti(O-2,6-iPr2Ph)Cl2]2 (4) exhibit an increase of molecular weight as well as comparable or even higher catalytic activity in ethylene (2 and 4) and styrene (3 and 4) polymerization than their mononuclear counterparts.
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2016-05-05
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