Biphenylene-Bridged Dinuclear Group 4 Metal Complexes: Enhanced Polymerization Properties in Olefin Polymerization
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https://figshare.com/articles/dataset/Biphenylene_Bridged_Dinuclear_Group_4_Metal_Complexes_Enhanced_Polymerization_Properties_in_Olefin_Polymerization/3277036
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资源简介:
The well-defined, novel dinuclear group 4
metal complexes [4,4‘-(C6H4)2(C5Me4)2][CpZrX2]2 (X = Cl
(2a), Me (2b)), [4,4‘-(C6H4)2(C5Me4)2][TiCl3]2 (3), and
[4,4‘-(C6H4)2(C5Me4)2][Ti(O-2,6-iPr2Ph)Cl2]2 (4) exhibit
an increase of molecular weight as well as comparable
or even higher catalytic activity in ethylene (2 and 4)
and styrene (3 and 4) polymerization than their mononuclear counterparts.
创建时间:
2016-05-05



