Biphenylene-Bridged Dinuclear Group 4 Metal Complexes: Enhanced Polymerization Properties in Olefin Polymerization
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The well-defined, novel dinuclear group 4 metal complexes [4,4‘-(C6H4)2(C5Me4)2][CpZrX2]2 (X = Cl (2a), Me (2b)), [4,4‘-(C6H4)2(C5Me4)2][TiCl3]2 (3), and [4,4‘-(C6H4)2(C5Me4)2][Ti(O-2,6-iPr2Ph)Cl2]2 (4) exhibit an increase of molecular weight as well as comparable or even higher catalytic activity in ethylene (2 and 4) and styrene (3 and 4) polymerization than their mononuclear counterparts.
创建时间：
2016-05-05
