Bonding and Reactivity of a Dicopper(I) μ‑Boryl Cation
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A siloxide-bridged dicopper(I) cation reacts with bis(catecholato)diboron to form the boryl-bridged dicopper cation {[(SIDipp)Cu]2(μ-Bcat)}+ (SIDipp = 1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene; cat = 1,2-C6H4O2). The solid-state structure shows an acute angle about the boryl, with a short intermetallic distance. Density functional theory calculations indicate a small but significant copper–copper bond order. The boryl-bridged cation deprotonates phenylacetylene and reacts with methanol to form a hydride-bridged dicopper cation.
创建时间：
2016-02-12
