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Addition of S−H Bonds across Electron-Deficient Olefins Catalyzed by Well-Defined Copper(I) Thiolate Complexes

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NIAID Data Ecosystem2026-03-06 收录
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A series of monomeric (NHC)Cu(SR) (R = Ph or CH2Ph; NHC = N-heterocyclic carbene) complexes have been synthesized and fully characterized including single-crystal X-ray diffraction studies. These complexes catalyze the addition of S−H bonds across electron-deficient olefins to regioselectively produce “anti-Markovnikov” products.

创建时间:
2007-04-02
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