Identification of an Asymmetric Pauson−Khand Precatalyst
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https://figshare.com/articles/dataset/Identification_of_an_Asymmetric_Pauson_Khand_Precatalyst/3355831
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资源简介:
X-ray crystallographic analysis of red crystals
formed on mixing octacarbonyldicobalt(0) and BINAP,
combined with NMR evidence obtained from a catalytic
asymmetric Pauson−Khand reaction, suggests that this
complex is a precatalyst to this reaction and leads to a
new hypothesis for the role of axially chiral diphosphanes in the catalytic asymmetric Pauson−Khand
reaction.
创建时间:
2016-05-07



