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Identification of an Asymmetric Pauson−Khand Precatalyst

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NIAID Data Ecosystem2026-03-06 收录
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X-ray crystallographic analysis of red crystals formed on mixing octacarbonyldicobalt(0) and BINAP, combined with NMR evidence obtained from a catalytic asymmetric Pauson−Khand reaction, suggests that this complex is a precatalyst to this reaction and leads to a new hypothesis for the role of axially chiral diphosphanes in the catalytic asymmetric Pauson−Khand reaction.

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2016-05-07
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