Synthesis, Crystal Structure, and Optical Properties of a Three-Dimensional Quaternary Hg–In–S–Cl Chalcohalide: Hg<sub>7</sub>InS<sub>6</sub>Cl<sub>5</sub>
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A crystalline three-dimensional (3D) quaternary chalcohalide, Hg7InS6Cl5 (1), has been synthesized through a solid-state reaction under medium temperature. It is the first example in the family of the Hg–IIIA–Q–X (Q = S, Se, Te; X = F, Cl, Br, I) systems. Compound 1 features a 3D network and has an optical band gap of 2.54 eV.
创建时间：
2012-04-16
