Synthesis of Highly Twisted and Fully π‑Conjugated Porphyrinic Oligomers
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https://figshare.com/articles/dataset/Synthesis_of_Highly_Twisted_and_Fully_Conjugated_Porphyrinic_Oligomers/2047008
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资源简介：
Highly
twisted π-conjugated molecules have been attractive
but challenging targets. We report here an efficient synthesis of
highly twisted diporphyrins with 126° and 136° twist angles
that involves an oxidative fusion reaction of planar aminoporphyrin
precursors at room temperature. Repeated amination–oxidative
fusion sequences provide a unidirectionally twisted tetramer. The
twisting angle of the tetramer is 298°.
创建时间：
2015-12-17
