Preorganization in Highly Enantioselective Diaza-Cope Rearrangement Reaction
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https://figshare.com/articles/dataset/Preorganization_in_Highly_Enantioselective_Diaza_Cope_Rearrangement_Reaction/3254320
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资源简介:
Crystal structure and activation entropy data indicate that H-bond directed diaza-Cope rearrangement of chiral diimines takes place with a high degree of preorganization. CD spectroscopy and HPLC data show that there is inversion of stereochemistry for the reaction with excellent enantioselectivity.
创建时间:
2016-05-05



