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Coordination-Driven Self-Assembly of Supramolecular Cages: Heteroatom-Containing and Complementary Trigonal Prisms

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https://figshare.com/articles/dataset/Coordination-Driven_Self-Assembly_of_Supramolecular_Cages_Heteroatom-Containing_and_Complementary_Trigonal_Prisms/3649251
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The self-assembly of three nanoscopic prisms of approximate size 1 × 4 nm is reported. Tetrahedral carbon, silicon, and phosphorus were used as structure-defining elements in these coordination-based cages. A carbon-based assembly completes a pair of nanoscopic complementary 3-D structures. The formation of the structures is supported by multinuclear NMR, ESI FT-ICR mass spectrometry, and elemental analysis data.
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2016-08-18
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