Sterically Controlled Esterification on Bis(μ-hydroxo) Dioxovanadium Site in γ-H<sub>2</sub>SiV<sub>2</sub>W<sub>10</sub>O<sub>40</sub><sup>4-</sup>
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The esterification of a bis(μ-hydroxo) dioxovanadium site in divanadium-substituted silicotungstate, γ-H2SiV2W10O404-, with alcohols is sterically controlled: The secondary and tertiary alcohol esters are hardly formed (equilibrium constant < 0.01), and a large equilibrium constant of 75 is observed for the reaction with methanol.
创建时间：
2016-05-06
