Catalytic Alkenylation of Phenylpyridines with Terminal Alkynes by a [12]Metallacrown-6 Ruthenium(II) Compound
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资源简介：
Two new [12]metallacrown-6 compounds, [MII6(SMe)12] [M = Ru (1), Zn (2)], were constructed from a dimethyl sulfoxide decomposed methylthiol product to doubly bridged metal centers. The RuII compound can prompt alkenylation reactions of phenylpyridines with alkynes to generate monoalkenylated arylpyridines in moderate yields with high regioselectivity and stereoselectivity.
创建时间：
2016-02-25
