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X-ray spectroscopy of bimetallic catalysts for CO2 reduction reaction

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ESRF Portal2028-01-01 更新2026-04-23 收录
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https://doi.esrf.fr/10.15151/ESRF-ES-2020737014
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The development of membrane-electrode assembly flow cells has led to rapid progress in CO2 electrolysis and efforts are currently focused on enhancing catalysts to achieve superior selectivity and activity levels. Bimetallic catalysts have been proposed to enhance the selectivity of the reaction towards the production of C2+ products. The role of the nature of the catalyst and its electronic and atomic structural evolution during the reaction remains however ambiguous. To deepen our understanding of the correlation between the coordination environment of Cu-based bimetallic catalysts and the CO2RR properties, we propose to perform operando X-ray spectroscopy. This project is part of an MSCA-DN (ECOMATES - grant agreement No 101072830) with the development of a tender X-ray operando cell as deliverable. Our project aims at elucidating the local coordination environment and the dynamic behavior of bimetallic catalysts during operation by using ex-situ and operando X-ray spectroscopy.
提供机构:
Politecnico di Torino, DISAT - Dept. Applied Science and Technology, Corso Duca degli Abruzzi 24, 10129 Torino, Italy; European Institute for Membranes, University of Montpellier, 300 Avenue du Professeur Emile Jeanbrau, 34090 Montpellier, France; Institut Europeen des Membranes, Departement DM3, Place Eugene Bataillon, 34095 Montpellier, France; Istituto Italiano di Tecnologia, Center for Sustainable Future Technologies, Via Livorno 60 Torino, 10114, Torino, IT
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2028-01-01
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