Synthesis, Molecular Structure, and Reactivity of the First Strained [2]Silanickelocenophane
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The strained ansa-complex [(Me2Si)2Cp2Ni] was synthesized by dilithiaton of 1,2-bis(cyclopentadienyl)-1,1,2,2-tetramethyldisilane with BuLi and subsequent reaction with [NiCl2(dme)]. The molecular structure was confirmed by X-ray diffraction analysis. Reaction of the ansa-complex with nickeltetra(tert-butylisonitrile) leads to rearrangement of the ligand framework to form a dinuclear compound.
创建时间：
2007-12-31
