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Synthesis of heteroleptic yttrium and dysprosium 1,2,4-tris(trimethylsilyl)cyclopentadienyl complexes

NIAID Data Ecosystem2026-03-13 收录

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https://figshare.com/articles/dataset/Synthesis_of_heteroleptic_yttrium_and_dysprosium_1_2_4-tris_trimethylsilyl_cyclopentadienyl_complexes/17081267 数据链接链接失效反馈

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资源简介：

Characterisation data of complexes.

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创建时间：

2022-08-10

稀土金属有机配合物合成

氢硅烷化催化

The Yb(II) hydride complex (DIPP-nacnac)YbH·THF (3-Yb, DIPP-nacnac = CH{(CMe)(2,6-iPr2C6H3N)}2) was prepared by a mild metathesis reaction of (DIPP-nacnac)Yb[N(SiMe3)2]·THF with PhSiH3. 3-Yb crystalli

NIAID Data Ecosystem60

Synthesis and Characterization of Dysprosium and Lanthanum Bis(iminophosphorano)methanide and -methanediide Complexes

稀土金属有机配合物合成

配位化学

Attempts to prepare [Dy{C(PPh2NSiMe3)2}(I)(THF)2] (1) from in situ prepared “[Dy(Bn)2(I)(THF)3]” (“2”; Bn = C6H5CH2) and H2C(PPh2NSiMe3)2 resulted in the isolation of [Dy{CH(PPh2NSiMe3)2}(I)2(THF)] (3

NIAID Data Ecosystem40

Sidearm Effects. Synthesis, Structural Characterization, and Reactivity of Lanthanides Incorporating a Linked Carboranyl-Indenyl Ligand with a Tethered Amine Group

稀土金属有机配合物合成

硼烷配位化学

A new amine-functionalized carboranyl-indenyl hybrid ligand shows unique properties in stabilizing various kinds of lanthanocene chloride complexes via increasing steric effects imposed by the coordin

NIAID Data Ecosystem20

Lanthanide Terminal Hydride Complexes Bearing Two Sterically Demanding C 5 Me 4 SiMe 3 Ligands. Synthesis, Structure, and Reactivity

稀土金属有机配合物合成

金属有机化合物反应

The acid−base reaction between lanthanide tris(alkyl) complexes Ln(CH2SiMe3)3(THF)2 and 2 equiv of HC5Me4SiMe3 in THF or hexane at room temperature resulted in the formation of metallocene complexes [

NIAID Data Ecosystem50

Synthesis and Stability of Homoleptic Metal(III) Tetramethylaluminates

稀土金属有机配合物合成

配合物稳定性预测

Whereas a number of homoleptic metal(III) tetramethylaluminates M(AlMe4)3 of the rare earth metals have proven accessible, the stability of these compounds varies strongly among the metals, with some

NIAID Data Ecosystem20

Synthesis of heteroleptic yttrium and dysprosium 1,2,4-tris(trimethylsilyl)cyclopentadienyl complexes

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