five

A Short Biomimetic Approach to the Fully Functionalized Bicyclic Framework of Type A Acylphloroglucinols

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https://figshare.com/articles/dataset/A_Short_Biomimetic_Approach_to_the_Fully_Functionalized_Bicyclic_Framework_of_Type_A_Acylphloroglucinols/2825113
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资源简介:
A biomimetic approach toward type A polyprenylated acylphloroglucinols (PPAPs) is described. The method is based on a C-alkylation−cation cyclization reaction sequence, leading to a convenient buildup of molecular complexity, employing the simple and readily available deoxycohumulone and an appropriately functionalized hydroxy halide. Thus, a versatile construction of the fully functionalized bicyclic framework of type A PPAPs (5) was achieved.
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2016-02-25
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