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Synthesis and Electrochemistry of Undeca-substituted Metallo-benzoylbiliverdins

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https://figshare.com/articles/dataset/Synthesis_and_Electrochemistry_of_Undeca_substituted_Metallo_benzoylbiliverdins/3237061
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The high-yield preparation of metallo-benzoylbiliverdins 9, 10, and 11 from either oxidation of dodeca-substituted porphyrin 6 in the presence of NaNO2/TFA and air followed by metalation or by reaction of the Ni(II) or Cu(II) complexes of 6 with m-chloroperoxybenzoic acid in pyridine under air is reported. The X-ray structures of complexes 9 and 10 and the electrochemistry and spectroelectrochemistry of metallo-benzoylbiliverdins 9−11 are presented and discussed.
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2016-05-05
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