Synthesis and Electrochemistry of Undeca-substituted Metallo-benzoylbiliverdins
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https://figshare.com/articles/dataset/Synthesis_and_Electrochemistry_of_Undeca_substituted_Metallo_benzoylbiliverdins/3237061
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资源简介:
The high-yield preparation of metallo-benzoylbiliverdins 9, 10, and 11 from either oxidation of dodeca-substituted
porphyrin 6 in the presence of NaNO2/TFA and air followed by metalation or by reaction of the Ni(II) or Cu(II)
complexes of 6 with m-chloroperoxybenzoic acid in pyridine under air is reported. The X-ray structures of complexes
9 and 10 and the electrochemistry and spectroelectrochemistry of metallo-benzoylbiliverdins 9−11 are presented
and discussed.
创建时间:
2016-05-05



