Polymeric, Molecular and Ionic Organotin Complexes Containing Hypoxanthine, Adenine and 2‑Aminopurine. Synthesis and Supramolecular Structures
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https://figshare.com/articles/dataset/Polymeric_Molecular_and_Ionic_Organotin_Complexes_Containing_Hypoxanthine_Adenine_and_2_Aminopurine_Synthesis_and_Supramolecular_Structures/2218534
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资源简介：
The
reaction of L1H [L1H = 3-(N9-hypoxanthyl)propanoic acid]
with Me3SnCl or (n-Bu3Sn)2O afforded the 1D coordination polymers [Me3Sn(L1)]n (1) and [n-Bu3Sn(L1)]n (2), respectively.
A similar reaction between L2H [3-{N9-(2-aminopurinyl)}propanoic
acid] with (Ph3Sn)2O in a 2:1 ratio afforded
a dimer [(L2)(Ph3Sn)L2{Ph3Sn(H2O)}]·3CH3OH·3H2O (3). The reactions of 2-(N9-adeninyl)acetic
acid (L3H) and 3-(N9-adeninyl)propanoic acid (L4H) with (Ph3Sn)2O in a 2:1 ratio afforded insoluble intractable
products, which, upon addition of dilute HCl in methanol, afforded
[{Ph2SnCl3(H2O)}(HL3Me)2Cl]·H2O (4) and [(Ph2SnCl4)(HL4Me)2] (5). Complexes 1–5 show an extensive
supramolecular organization in the solid state as a result of several
intermolecular interactions, prominent among which are the interactions
between the nucleobases.
创建时间：
2016-02-16
