Synthesis of an Arylbromosilylene–Platinum Complex by Using a 1,2-Dibromodisilene As a Silylene Source
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https://figshare.com/articles/dataset/Synthesis_of_an_Arylbromosilylene_Platinum_Complex_by_Using_a_1_2_Dibromodisilene_As_a_Silylene_Source/2551120
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资源简介：
Kinetically stabilized 1,2-dibromodisilene, Bbt(Br)SiSi(Br)Bbt
(Bbt = 2,6-bis[bis(trimethylsilyl)methyl]-4-[tris(trimethylsilyl)methyl]phenyl)
(2), was treated with [Pt(PCy3)2] to afford the corresponding arylbromosilylene–Pt complex,
Bbt(Br)SiPt(PCy3)2 (1),
as stable orange crystals. The molecular
structure of 1 was elucidated by spectroscopic and X-ray
crystallographic analyses. The nature of the Si–Pt bond in 1 was investigated with the aid of DFT calcualtions.
创建时间：
2016-02-22
