Light- and Thermal-Activated Olefin Metathesis of Hindered Substrates
收藏Figshare2017-12-28 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Light-_and_Thermal-Activated_Olefin_Metathesis_of_Hindered_Substrates/5739972
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资源简介：
Efficient light- and thermal-activated metathesis reactions of tetra-substituted olefins were obtained by the S-chelated ruthenium precatalyst Tol-SCF3. Its reactivity in a series of benchmark olefin metathesis reactions was compared to previously reported Mes-SCF3 and a novel sterically congested S-chelated complex, Dipp-SCF3. Tol-SCF3 is thus the first latent catalyst proven to be capable of promoting olefin metathesis of demanding substrates upon light stimulation at room temperature.
创建时间：
2017-12-28
