Formation of Heterobimetallic Zirconium/Cobalt Diimido Complexes via a Four-Electron Transformation
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https://figshare.com/articles/dataset/Formation_of_Heterobimetallic_Zirconium_Cobalt_Diimido_Complexes_via_a_Four_Electron_Transformation/2248837
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资源简介：
The reactivity of the reduced heterobimetallic
complex Zr(iPrNPiPr2)3CoN2 (1)
toward aryl azides was examined, revealing a four-electron redox transformation
to afford unusual heterobimetallic zirconium/cobalt diimido complexes.
In the case of p-tolyl azide, the diamagnetic C3-symmetric bis(terminal imido) complex 3 is formed, but mesityl azide instead leads to asymmetric
complex 4 featuring a bridging imido fragment.
创建时间：
2014-10-06
