Synthesis and Reactivity of Bicyclo[3.2.1]octanoid-Derived Cyclopropanes
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https://figshare.com/articles/dataset/Synthesis_and_Reactivity_of_Bicyclo_3_2_1_octanoid_Derived_Cyclopropanes/2576047
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Photochemical oxa-di-π-methane rearrangement of bicyclo[3.2.1]octanoid scaffolds affords multifunctional, donor–acceptor cyclopropanes. A related photochemical reaction of an iminium ether substrate uncovered an unprecedented aza-di-π-methane rearrangement of a β,γ-unsaturated iminium. Donor–acceptor cyclopropanes have been evaluated as substrates for reactions generating several new chemotypes.
创建时间:
2016-02-22



