Synthesis of the Norjatrophane Diterpene (−)-15-Acetyl-3-propionyl- 17-norcharaciol
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https://figshare.com/articles/dataset/Synthesis_of_the_Norjatrophane_Diterpene_15_Acetyl_3_propionyl_17_norcharaciol/3227743
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资源简介:
A scalable enantioselective synthesis of the nonnatural 17-norjatrophane diterpene 3-propionyl-15-acetyl-17-norcharaciol is described. Key
C/C-connecting transformations are an Evans aldol reaction, an intramolecular carbonyl ene reaction, a Horner−Wadsworth−Emmons olefination,
and a ring-closing metathesis for the formation of a 12-membered carbacycle.
创建时间:
2016-05-05



