Functional Mononitrosyl Diiron(II) Complex Mediates the Reduction of NO to N2O with Relevance for Flavodiiron NO Reductases
收藏Figshare2018-09-27 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Functional_Mononitrosyl_Diiron_II_Complex_Mediates_the_Reduction_of_NO_to_N_sub_2_sub_O_with_Relevance_for_Flavodiiron_NO_Reductases/5484967
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Reaction of [Fe2(N-Et-HPTB)(CH3COS)](BF4)2 (1) with (NO)(BF4) produces a nonheme mononitrosyl diiron(II) complex, [Fe2(N-Et-HPTB)(NO)(DMF)3](BF4)3 (2). Complex 2 is the first example of a [FeII{Fe(NO)}7] species and is also the first example of a mononitrosyl diiron(II) complex that mediates the reduction of NO to N2O. This work describes the selective synthesis, detailed characterization and NO reduction activity of 2 and thus provides new insights regarding the mechanism of flavodiiron nitric oxide reductases.
创建时间：
2018-09-27
