Synthesis of (±)-Aphanorphine Using Rh-Catalyzed Cyclohydrocarbonylation
收藏NIAID Data Ecosystem2026-03-10 收录
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A facile formal synthesis to aphanorphine and its analogue is described, featuring Rh-catalyzed cyclohydrocarbonylation of 2-aminodihydronaphthalene to the bridged benzazepine core. Subsequent introduction of the methyl group and functional group transformation complete the synthesis of aphanorphine and its analogue over eight steps.
创建时间：
2017-07-24
