Spiro Tröger’s Base Derivatives: Another Structural Phoenix?
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https://figshare.com/articles/dataset/Spiro_Tro_ger_s_Base_Derivatives_Another_Structural_Phoenix_/2776486
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Recently, naphthalenoide derivatives of Tröger’s base (TB) have become important as structural compartments of molecular tweezers and compounds with high specific rotation. The formation of TB derivatives and byproducts from naphthalen-2-amine, methyl 6-aminonaphthalene-2-carboxylate, and anthracen-2-amine was studied. It was discovered that the formation of a naphthalenoide TB derivative is followed by the formation of a unique structural isomer of TB: spiroTB.
创建时间:
2010-04-16



