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Spiro Tröger’s Base Derivatives: Another Structural Phoenix?

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NIAID Data Ecosystem2026-03-06 收录
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Recently, naphthalenoide derivatives of Tröger’s base (TB) have become important as structural compartments of molecular tweezers and compounds with high specific rotation. The formation of TB derivatives and byproducts from naphthalen-2-amine, methyl 6-aminonaphthalene-2-carboxylate, and anthracen-2-amine was studied. It was discovered that the formation of a naphthalenoide TB derivative is followed by the formation of a unique structural isomer of TB: spiroTB.

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2010-04-16
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