Generation of α‑Imino Gold Carbenes through Gold-Catalyzed Intermolecular Reaction of Azides with Ynamides
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https://figshare.com/articles/dataset/Generation_of_Imino_Gold_Carbenes_through_Gold_Catalyzed_Intermolecular_Reaction_of_Azides_with_Ynamides/2202700
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资源简介：
The
generation of α-imino gold carbenes via gold-catalyzed
intermolecular reaction of azides and ynamides is disclosed. This
new methodology allows for highly regioselective access to valuable
2-aminoindoles and 3-amino-β-carbolines in generally good to
excellent yields. A mechanistic rationale for this tandem reaction,
especially for the observed high regioselectivity, is supported by
DFT calculations.
创建时间：
2016-02-15
